Here are some new photos of Jennifer Aniston and some of the other ladies involved in Lifetime’s Five, at the premiere in Washington, D.C. last night. Aniston didn’t get dressed up to the nines – she just wore a simple blazer and a great pair of black boots – I think those boots are the same ones she’s been wearing all over NYC. She looks nice.

Before the D.C. premiere, Aniston did a breast cancer awareness event with Jill Biden, wife of VPOTUS, in Alexandria, Virginia:

It’s not often you hear the names “Jill Biden” and “Jennifer Aniston” in the same sentence. But the two women came together today in support of breast cancer research, visiting the the Breast Care Center at the Inova Alexandria Hospital at Mark Center in Virginia.

The two chic blondes were joined by Secretary of Health and Human Services Kathleen Sebelius and Kristin Hahn, co-producer of Aniston’s newest film project, “Five.” The Lifetime film series, composed of five short movies, chronicles different women’s experiences with breast cancer.

The four women toured the center and met with doctors, who listened to the group talk about their own experiences with cancer.

Biden said that her “personal involvement with breast cancer started 20 years ago when several of my friends got breast cancer,” compelling her to create a program in Delaware that invites doctors educate on the subject in classrooms.

Aniston, pool reports wrote, was particularly affected by nurse Ami Bhavsar, who spoke about the difficulties of helping patients without insurance.

The women’s outfits did not distract from the experience, as Biden wore a very SLOTUS-esque ensemble consisting of a purple jersey dress, nude pumps and a long, silver necklace. Aniston kept it cool in jeans and a black sweater.

One unexpected accessory? A heart-shaped ring on the movie star’s left hand, which had the press room buzzing after the event.

[From HuffPo]

You can see the photos from that event here, at the Mail, but there are also some shots where you can see Aniston’s rings in these premiere photos too.

In other Aniston news, do remember that she did a “Between Two Ferns” bit with Zach Galifianakis? Here’s the video:

Well, Zach discussed the behind-the-scenes story during a recent interview, and it’s just…weird:

Jennifer Aniston is long over her split from Brad Pitt — and according to Zach Galifianakis, she has no interest in taking a walk down memory lane. During the New Yorker Festival in New York City Saturday, the Hangover star revealed that the 42-year-old actress wasn’t keen on his idea to use a Pitt look-alike for his Between Two Ferns comedy segment on Funny or Die.

“I had found this guy [in our hotel] who looked exactly like Brad Pitt. I wanted to use that in some way,” Galifianakis, 42, recalled. “I said, ‘Jennifer, I have this guy who looks like Brad Pitt. I want to make it seem like I think it’s him.'”

“She looked at me like, ‘What the f–k?'” an embarrassed Galifianakis admitted. “And I totally agreed with her. How rude of me to do that! Why would she want to talk about that? She get inundated with that sh-t all the time. I totally understood.”

A dejected Galifianakis then met with the look-alike to “tell him sorry that we couldn’t do the bit.”

“People are pretty game, usually,” Galifianakis said of his guests on Between Two Ferns. “It’s a fun, stupid thing to do.”

After Aniston nixed his original idea, Galifianakis enlisted former MTV reality star Tila Tequila, 29, to appear in the skit. During the four-minute clip, Galifianakis made it clear that he favored Tequila, prompting Aniston to (jokingly) storm off.

[From Us Weekly]

So instead of a Brad Pitt look-alike, Aniston opted for Tila Tequila? That’s like Sophie’s Choice, dude. And I’m kind of surprised that Zach is so nice about the whole thing – this is the guy who will talk sh-t about any celebrity. But not Jennifer. Probably because she was game for pretty much anything – anything besides a Brad Pitt look-alike.

Photos courtesy of Fame.